Rhodium in PDB 3gsk: A Bulky Rhodium Complex Bound to An Adenosine-Adenosine Dna Mismatch

The structure of A Bulky Rhodium Complex Bound to An Adenosine-Adenosine Dna Mismatch, PDB code: 3gsk was solved by B.M.Zeglis, V.C.Pierre, J.T.Kaiser, J.K.Barton, with X-Ray Crystallography technique. A brief refinement statistics is given in the table below:

Resolution Low / High (Å)	20.27 / 1.60
Space group	P 32 2 1
Cell size a, b, c (Å), α, β, γ (°)	48.337, 48.337, 69.505, 90.00, 90.00, 120.00
R / Rfree (%)	18.4 / 22.7

The structure of A Bulky Rhodium Complex Bound to An Adenosine-Adenosine Dna Mismatch also contains other interesting chemical elements:

Arsenic

(As)

2 atoms

The binding sites of Rhodium atom in the A Bulky Rhodium Complex Bound to An Adenosine-Adenosine Dna Mismatch (pdb code 3gsk). This binding sites where shown within 5.0 Angstroms radius around Rhodium atom.
In total 2 binding sites of Rhodium where determined in the A Bulky Rhodium Complex Bound to An Adenosine-Adenosine Dna Mismatch, PDB code: 3gsk:
Jump to Rhodium binding site number: 1; 2;

Rhodium binding site 1 out of 2 in the A Bulky Rhodium Complex Bound to An Adenosine-Adenosine Dna Mismatch


Mono view


Stereo pair view

A full contact list of Rhodium with other atoms in the Rh binding site number 1 of A Bulky Rhodium Complex Bound to An Adenosine-Adenosine Dna Mismatch within 5.0Å range: probe atom residue distance (Å) B Occ B:Rh2001 b:33.9 occ:1.00 RH B:R1C2001 0.0 33.9 1.0 N5 B:R1C2001 1.8 37.3 1.0 N6 B:R1C2001 1.8 38.5 1.0 N4 B:R1C2001 1.8 39.3 1.0 N2 B:R1C2001 1.8 45.2 1.0 N1 B:R1C2001 1.9 44.9 1.0 N3 B:R1C2001 1.9 40.7 1.0 C16 B:R1C2001 2.7 42.3 1.0 C22 B:R1C2001 2.7 35.3 1.0 C21 B:R1C2001 2.7 37.3 1.0 C15 B:R1C2001 2.7 38.5 1.0 C6 B:R1C2001 2.8 35.5 1.0 C5 B:R1C2001 2.8 35.8 1.0 C10 B:R1C2001 2.8 40.3 1.0 C11 B:R1C2001 2.9 41.8 1.0 C1 B:R1C2001 2.9 35.1 1.0 C20 B:R1C2001 2.9 36.1 1.0 C17 B:R1C2001 4.0 38.9 1.0 C14 B:R1C2001 4.1 44.8 1.0 C7 B:R1C2001 4.1 35.3 1.0 C4 B:R1C2001 4.1 30.6 1.0 C9 B:R1C2001 4.1 45.4 1.0 C19 B:R1C2001 4.1 38.3 1.0 C23 B:R1C2001 4.2 28.9 1.0 C12 B:R1C2001 4.2 39.6 1.0 O B:HOH31 4.2 42.5 1.0 C2 B:R1C2001 4.2 32.3 1.0 C38 B:R1C2001 4.2 33.0 1.0 C25 B:R1C2001 4.6 41.4 1.0 C18 B:R1C2001 4.6 37.1 1.0 C13 B:R1C2001 4.6 38.3 1.0 C8 B:R1C2001 4.7 40.2 1.0 H1' A:DC10 4.7 48.8 1.0 C3 B:R1C2001 4.7 30.4 1.0 O A:HOH17 4.8 44.6 1.0 H14 B:R1C2001 4.9 53.7 1.0 O2 A:DT8 4.9 43.6 1.0 C24 B:R1C2001 4.9 33.0 1.0 H4 B:R1C2001 4.9 36.8 1.0 C37 B:R1C2001 4.9 35.7 1.0

Rhodium binding site 2 out of 2 in the A Bulky Rhodium Complex Bound to An Adenosine-Adenosine Dna Mismatch


Mono view


Stereo pair view

A full contact list of Rhodium with other atoms in the Rh binding site number 2 of A Bulky Rhodium Complex Bound to An Adenosine-Adenosine Dna Mismatch within 5.0Å range: probe atom residue distance (Å) B Occ A:Rh2002 b:32.8 occ:1.00 RH A:R1C2002 0.0 32.8 1.0 N4 A:R1C2002 1.8 44.1 1.0 N5 A:R1C2002 1.8 40.6 1.0 N6 A:R1C2002 1.8 34.8 1.0 N1 A:R1C2002 1.9 31.6 1.0 N3 A:R1C2002 1.9 40.0 1.0 N2 A:R1C2002 1.9 37.1 1.0 C16 A:R1C2002 2.7 38.2 1.0 C15 A:R1C2002 2.7 39.1 1.0 C5 A:R1C2002 2.7 33.8 1.0 C6 A:R1C2002 2.7 30.9 1.0 C21 A:R1C2002 2.8 31.4 1.0 C22 A:R1C2002 2.8 30.9 1.0 C20 A:R1C2002 2.9 36.4 1.0 C11 A:R1C2002 2.9 40.6 1.0 C10 A:R1C2002 2.9 38.5 1.0 C1 A:R1C2002 2.9 32.9 1.0 C17 A:R1C2002 4.0 39.0 1.0 C4 A:R1C2002 4.1 31.8 1.0 C14 A:R1C2002 4.1 36.1 1.0 C7 A:R1C2002 4.1 34.9 1.0 C19 A:R1C2002 4.1 41.5 1.0 O A:HOH49 4.2 42.1 1.0 C9 A:R1C2002 4.2 44.2 1.0 C12 A:R1C2002 4.2 37.0 1.0 C38 A:R1C2002 4.2 30.3 1.0 C2 A:R1C2002 4.2 27.5 1.0 C23 A:R1C2002 4.2 30.9 1.0 C18 A:R1C2002 4.6 34.5 1.0 C25 A:R1C2002 4.7 32.4 1.0 H1' B:DC10 4.7 39.5 1.0 C3 A:R1C2002 4.7 28.0 1.0 C13 A:R1C2002 4.7 37.0 1.0 C8 A:R1C2002 4.7 37.1 1.0 O B:HOH28 4.8 47.6 1.0 H4 A:R1C2002 4.8 38.2 1.0 C37 A:R1C2002 4.9 33.6 1.0 H14 A:R1C2002 4.9 43.4 1.0 O2 B:DT8 4.9 35.8 1.0

B.M.Zeglis, V.C.Pierre, J.T.Kaiser, J.K.Barton. A Bulky Rhodium Complex Bound to An Adenosine-Adenosine Dna Mismatch: General Architecture of the Metalloinsertion Binding Mode Biochemistry V. 48 4247 2009.
ISSN: ISSN 0006-2960
PubMed: 19374348
DOI: 10.1021/BI900194E