Rhodium in PDB 3gsj: A Bulky Rhodium Complex Bound to An Adenosine-Adenosine Dna Mismatch

The structure of A Bulky Rhodium Complex Bound to An Adenosine-Adenosine Dna Mismatch, PDB code: 3gsj was solved by B.M.Zeglis, V.C.Pierre, J.T.Kaiser, J.K.Barton, with X-Ray Crystallography technique. A brief refinement statistics is given in the table below:

Resolution Low / High (Å)	27.59 / 1.80
Space group	P 43 21 2
Cell size a, b, c (Å), α, β, γ (°)	39.020, 39.020, 57.420, 90.00, 90.00, 90.00
R / Rfree (%)	18.3 / 21.3

The structure of A Bulky Rhodium Complex Bound to An Adenosine-Adenosine Dna Mismatch also contains other interesting chemical elements:

Chlorine	(Cl)	1 atom
Sodium	(Na)	1 atom

The binding sites of Rhodium atom in the A Bulky Rhodium Complex Bound to An Adenosine-Adenosine Dna Mismatch (pdb code 3gsj). This binding sites where shown within 5.0 Angstroms radius around Rhodium atom.
In total 2 binding sites of Rhodium where determined in the A Bulky Rhodium Complex Bound to An Adenosine-Adenosine Dna Mismatch, PDB code: 3gsj:
Jump to Rhodium binding site number: 1; 2;

Rhodium binding site 1 out of 2 in the A Bulky Rhodium Complex Bound to An Adenosine-Adenosine Dna Mismatch


Mono view


Stereo pair view

A full contact list of Rhodium with other atoms in the Rh binding site number 1 of A Bulky Rhodium Complex Bound to An Adenosine-Adenosine Dna Mismatch within 5.0Å range: probe atom residue distance (Å) B Occ A:Rh2001 b:22.7 occ:1.00 RH A:R1C2001 0.0 22.7 1.0 N5 A:R1C2001 1.8 18.4 1.0 N6 A:R1C2001 1.8 19.1 1.0 N3 A:R1C2001 1.9 25.9 1.0 N4 A:R1C2001 1.9 23.4 1.0 N2 A:R1C2001 1.9 22.3 1.0 N1 A:R1C2001 2.0 20.5 1.0 C22 A:R1C2001 2.8 18.2 1.0 C15 A:R1C2001 2.8 25.9 1.0 C16 A:R1C2001 2.8 26.9 1.0 C21 A:R1C2001 2.8 18.6 1.0 C5 A:R1C2001 2.9 20.6 1.0 C6 A:R1C2001 2.9 20.0 1.0 C1 A:R1C2001 2.9 20.4 1.0 C20 A:R1C2001 3.0 23.9 1.0 C10 A:R1C2001 3.0 23.0 1.0 C11 A:R1C2001 3.0 23.9 1.0 O A:HOH58 4.1 43.1 1.0 C14 A:R1C2001 4.2 24.9 1.0 C17 A:R1C2001 4.2 26.9 1.0 C23 A:R1C2001 4.2 17.7 1.0 C19 A:R1C2001 4.2 26.3 1.0 C4 A:R1C2001 4.2 21.6 1.0 C2 A:R1C2001 4.3 22.5 1.0 C38 A:R1C2001 4.3 19.1 1.0 C7 A:R1C2001 4.3 23.2 1.0 C12 A:R1C2001 4.3 26.0 1.0 C9 A:R1C2001 4.3 24.0 1.0 O A:HOH35 4.3 37.7 1.0 C25 A:R1C2001 4.7 18.9 1.0 C18 A:R1C2001 4.8 25.4 1.0 C13 A:R1C2001 4.8 24.5 1.0 C3 A:R1C2001 4.8 21.5 1.0 C8 A:R1C2001 4.9 22.0 1.0 O A:HOH14 4.9 31.6 1.0 C24 A:R1C2001 5.0 19.1 1.0

Rhodium binding site 2 out of 2 in the A Bulky Rhodium Complex Bound to An Adenosine-Adenosine Dna Mismatch


Mono view


Stereo pair view

A full contact list of Rhodium with other atoms in the Rh binding site number 2 of A Bulky Rhodium Complex Bound to An Adenosine-Adenosine Dna Mismatch within 5.0Å range: probe atom residue distance (Å) B Occ A:Rh2002 b:25.1 occ:0.50 RH A:R1C2002 0.0 25.1 0.5 N6 A:R1C2002 1.8 22.8 0.5 N5 A:R1C2002 1.8 22.5 0.5 N3 A:R1C2002 1.8 23.1 0.5 N2 A:R1C2002 1.8 24.4 0.5 N4 A:R1C2002 1.9 24.3 0.5 N1 A:R1C2002 1.9 23.7 0.5 C22 A:R1C2002 2.7 22.0 0.5 C21 A:R1C2002 2.7 22.2 0.5 C15 A:R1C2002 2.7 24.9 0.5 C16 A:R1C2002 2.8 22.2 0.5 C6 A:R1C2002 2.8 25.1 0.5 C5 A:R1C2002 2.8 22.7 0.5 C10 A:R1C2002 2.9 22.8 0.5 C11 A:R1C2002 2.9 22.4 0.5 C1 A:R1C2002 2.9 24.0 0.5 C20 A:R1C2002 3.0 23.1 0.5 C14 A:R1C2002 4.1 22.7 0.5 C7 A:R1C2002 4.1 22.9 0.5 C17 A:R1C2002 4.1 23.0 0.5 C23 A:R1C2002 4.2 21.7 0.5 C9 A:R1C2002 4.2 23.8 0.5 C12 A:R1C2002 4.2 22.8 0.5 C4 A:R1C2002 4.2 23.1 0.5 C38 A:R1C2002 4.2 21.6 0.5 C2 A:R1C2002 4.2 23.0 0.5 C19 A:R1C2002 4.3 22.8 0.5 C13 A:R1C2002 4.7 22.7 0.5 C8 A:R1C2002 4.7 23.0 0.5 C18 A:R1C2002 4.7 22.5 0.5 C3 A:R1C2002 4.7 24.0 0.5 O A:HOH68 4.8 38.8 1.0 C25 A:R1C2002 4.8 22.5 0.5 C37 A:R1C2002 4.9 21.9 0.5 C24 A:R1C2002 5.0 21.8 0.5

B.M.Zeglis, V.C.Pierre, J.T.Kaiser, J.K.Barton. A Bulky Rhodium Complex Bound to An Adenosine-Adenosine Dna Mismatch: General Architecture of the Metalloinsertion Binding Mode Biochemistry V. 48 4247 2009.
ISSN: ISSN 0006-2960
PubMed: 19374348
DOI: 10.1021/BI900194E