Rhodium in PDB 2o1i: Rh(Bpy)2CHRYSI Complexed to Mismatched Dna

The structure of Rh(Bpy)2CHRYSI Complexed to Mismatched Dna, PDB code: 2o1i was solved by V.C.Pierre, J.T.Kaiser, J.K.Barton, with X-Ray Crystallography technique. A brief refinement statistics is given in the table below:

Resolution Low / High (Å)	N/A / 1.10
Space group	P 43 21 2
Cell size a, b, c (Å), α, β, γ (°)	38.740, 38.740, 57.560, 90.00, 90.00, 90.00
R / Rfree (%)	n/a / 20.4

The binding sites of Rhodium atom in the Rh(Bpy)2CHRYSI Complexed to Mismatched Dna (pdb code 2o1i). This binding sites where shown within 5.0 Angstroms radius around Rhodium atom.
In total 3 binding sites of Rhodium where determined in the Rh(Bpy)2CHRYSI Complexed to Mismatched Dna, PDB code: 2o1i:
Jump to Rhodium binding site number: 1; 2; 3;

Rhodium binding site 1 out of 3 in the Rh(Bpy)2CHRYSI Complexed to Mismatched Dna


Mono view


Stereo pair view

A full contact list of Rhodium with other atoms in the Rh binding site number 1 of Rh(Bpy)2CHRYSI Complexed to Mismatched Dna within 5.0Å range: probe atom residue distance (Å) B Occ A:Rh1001 b:13.5 occ:0.24 RH A:R1C1001 0.0 13.5 0.2 RH A:R1C2011 0.5 15.4 0.3 N2 A:R1C2011 1.6 21.3 0.3 N3 A:R1C2011 1.6 13.0 0.3 N4 A:R1C2011 1.8 13.4 0.3 N6 A:R1C1001 1.8 16.6 0.2 N5 A:R1C1001 1.8 15.0 0.2 N4 A:R1C1001 1.8 16.8 0.2 N3 A:R1C1001 1.8 20.7 0.2 N2 A:R1C1001 1.8 11.5 0.2 N1 A:R1C1001 1.8 11.5 0.2 N1 A:R1C2011 2.0 17.5 0.3 N5 A:R1C2011 2.1 12.2 0.3 N6 A:R1C2011 2.2 12.3 0.3 C15 A:R1C2011 2.5 11.8 0.3 C10 A:R1C2011 2.5 22.4 0.3 C6 A:R1C2011 2.5 18.9 0.3 C16 A:R1C2011 2.6 9.6 0.3 C16 A:R1C1001 2.7 17.2 0.2 C15 A:R1C1001 2.7 19.6 0.2 C11 A:R1C2011 2.7 13.8 0.3 C5 A:R1C1001 2.7 10.8 0.2 C22 A:R1C1001 2.7 13.4 0.2 C5 A:R1C2011 2.7 15.5 0.3 C6 A:R1C1001 2.7 13.2 0.2 C21 A:R1C1001 2.7 13.4 0.2 C11 A:R1C1001 2.9 23.8 0.2 C10 A:R1C1001 2.9 11.4 0.2 C20 A:R1C1001 2.9 16.1 0.2 C1 A:R1C1001 2.9 10.9 0.2 C20 A:R1C2011 2.9 11.3 0.3 C1 A:R1C2011 3.2 15.0 0.3 C21 A:R1C2011 3.2 11.8 0.3 C22 A:R1C2011 3.2 12.0 0.3 C9 A:R1C2011 3.8 22.7 0.3 C7 A:R1C2011 3.8 19.5 0.3 C14 A:R1C2011 3.8 12.7 0.3 C17 A:R1C2011 3.9 11.8 0.3 C12 A:R1C2011 4.0 12.9 0.3 C14 A:R1C1001 4.0 21.2 0.2 C17 A:R1C1001 4.0 15.5 0.2 C7 A:R1C1001 4.0 14.9 0.2 C4 A:R1C1001 4.1 10.6 0.2 C4 A:R1C2011 4.1 15.5 0.3 C38 A:R1C1001 4.1 15.9 0.2 C19 A:R1C2011 4.1 13.3 0.3 C9 A:R1C1001 4.1 11.0 0.2 C12 A:R1C1001 4.2 23.2 0.2 C23 A:R1C1001 4.2 14.1 0.2 C19 A:R1C1001 4.2 14.5 0.2 C2 A:R1C1001 4.2 12.5 0.2 C8 A:R1C2011 4.4 20.3 0.3 C2 A:R1C2011 4.4 14.8 0.3 C13 A:R1C2011 4.5 12.9 0.3 C38 A:R1C2011 4.5 12.4 0.3 C18 A:R1C2011 4.6 11.9 0.3 C3 A:R1C1001 4.6 11.1 0.2 C23 A:R1C2011 4.6 14.7 0.3 C13 A:R1C1001 4.6 21.0 0.2 C18 A:R1C1001 4.6 15.3 0.2 C8 A:R1C1001 4.7 13.2 0.2 C25 A:R1C1001 4.7 16.8 0.2 C3 A:R1C2011 4.8 14.2 0.3 C37 A:R1C1001 4.8 15.7 0.2 C24 A:R1C1001 4.9 15.5 0.2 C25 A:R1C2011 5.0 15.9 0.3 O A:HOH2017 5.0 30.7 1.0

Rhodium binding site 2 out of 3 in the Rh(Bpy)2CHRYSI Complexed to Mismatched Dna


Mono view


Stereo pair view

A full contact list of Rhodium with other atoms in the Rh binding site number 2 of Rh(Bpy)2CHRYSI Complexed to Mismatched Dna within 5.0Å range: probe atom residue distance (Å) B Occ A:Rh2011 b:15.4 occ:0.26 RH A:R1C2011 0.0 15.4 0.3 RH A:R1C1001 0.5 13.5 0.2 N5 A:R1C1001 1.5 15.0 0.2 N6 A:R1C1001 1.6 16.6 0.2 N6 A:R1C2011 1.8 12.3 0.3 N2 A:R1C2011 1.8 21.3 0.3 N5 A:R1C2011 1.8 12.2 0.3 N4 A:R1C1001 1.8 16.8 0.2 N1 A:R1C2011 1.8 17.5 0.3 N4 A:R1C2011 1.8 13.4 0.3 N3 A:R1C2011 1.8 13.0 0.3 N1 A:R1C1001 2.0 11.5 0.2 N2 A:R1C1001 2.2 11.5 0.2 N3 A:R1C1001 2.2 20.7 0.2 C21 A:R1C1001 2.3 13.4 0.2 C22 A:R1C1001 2.3 13.4 0.2 C5 A:R1C2011 2.7 15.5 0.3 C22 A:R1C2011 2.7 12.0 0.3 C16 A:R1C2011 2.7 9.6 0.3 C6 A:R1C2011 2.7 18.9 0.3 C15 A:R1C2011 2.7 11.8 0.3 C20 A:R1C1001 2.7 16.1 0.2 C21 A:R1C2011 2.8 11.8 0.3 C16 A:R1C1001 2.8 17.2 0.2 C10 A:R1C2011 2.8 22.4 0.3 C11 A:R1C2011 2.9 13.8 0.3 C20 A:R1C2011 2.9 11.3 0.3 C1 A:R1C2011 2.9 15.0 0.3 C5 A:R1C1001 2.9 10.8 0.2 C15 A:R1C1001 3.0 19.6 0.2 C6 A:R1C1001 3.0 13.2 0.2 C1 A:R1C1001 3.0 10.9 0.2 C10 A:R1C1001 3.1 11.4 0.2 C11 A:R1C1001 3.3 23.8 0.2 C38 A:R1C1001 3.6 15.9 0.2 C23 A:R1C1001 3.7 14.1 0.2 C19 A:R1C1001 4.0 14.5 0.2 C14 A:R1C2011 4.0 12.7 0.3 C7 A:R1C2011 4.0 19.5 0.3 C4 A:R1C2011 4.1 15.5 0.3 C17 A:R1C2011 4.1 11.8 0.3 C17 A:R1C1001 4.1 15.5 0.2 C38 A:R1C2011 4.1 12.4 0.3 C9 A:R1C2011 4.1 22.7 0.3 C12 A:R1C2011 4.2 12.9 0.3 C23 A:R1C2011 4.2 14.7 0.3 C2 A:R1C2011 4.2 14.8 0.3 C19 A:R1C2011 4.2 13.3 0.3 C4 A:R1C1001 4.3 10.6 0.2 C7 A:R1C1001 4.3 14.9 0.2 C14 A:R1C1001 4.3 21.2 0.2 C2 A:R1C1001 4.3 12.5 0.2 C9 A:R1C1001 4.4 11.0 0.2 C37 A:R1C1001 4.4 15.7 0.2 C25 A:R1C1001 4.5 16.8 0.2 C12 A:R1C1001 4.5 23.2 0.2 C25 A:R1C2011 4.6 15.9 0.3 C24 A:R1C1001 4.6 15.5 0.2 C18 A:R1C1001 4.6 15.3 0.2 C33 A:R1C1001 4.6 15.8 0.2 C8 A:R1C2011 4.6 20.3 0.3 C32 A:R1C1001 4.7 16.3 0.2 C13 A:R1C2011 4.7 12.9 0.3 C18 A:R1C2011 4.7 11.9 0.3 C3 A:R1C2011 4.7 14.2 0.3 C3 A:R1C1001 4.8 11.1 0.2 C37 A:R1C2011 4.8 14.5 0.3 O A:HOH2017 4.8 30.7 1.0 C24 A:R1C2011 4.9 12.1 0.3 C8 A:R1C1001 4.9 13.2 0.2 C13 A:R1C1001 5.0 21.0 0.2 N6 A:DA6 5.0 20.4 1.0

Rhodium binding site 3 out of 3 in the Rh(Bpy)2CHRYSI Complexed to Mismatched Dna


Mono view


Stereo pair view

A full contact list of Rhodium with other atoms in the Rh binding site number 3 of Rh(Bpy)2CHRYSI Complexed to Mismatched Dna within 5.0Å range: probe atom residue distance (Å) B Occ A:Rh1002 b:15.4 occ:1.00 RH A:R1C1002 0.0 15.4 1.0 N3 A:R1C1002 1.9 16.9 1.0 N6 A:R1C1002 1.9 14.3 1.0 N4 A:R1C1002 1.9 17.1 1.0 N5 A:R1C1002 1.9 14.6 1.0 N1 A:R1C1002 1.9 14.0 1.0 N2 A:R1C1002 2.0 17.0 1.0 C22 A:R1C1002 2.8 14.0 1.0 C15 A:R1C1002 2.8 16.7 1.0 C21 A:R1C1002 2.8 13.8 1.0 C16 A:R1C1002 2.8 17.4 1.0 C6 A:R1C1002 2.9 15.6 1.0 C5 A:R1C1002 2.9 13.9 1.0 C20 A:R1C1002 2.9 18.1 1.0 C1 A:R1C1002 2.9 14.4 1.0 C11 A:R1C1002 3.0 17.0 1.0 C10 A:R1C1002 3.0 17.6 1.0 C14 A:R1C1002 4.1 19.9 1.0 C17 A:R1C1002 4.2 21.7 1.0 C7 A:R1C1002 4.2 17.1 1.0 C4 A:R1C1002 4.2 13.9 1.0 C23 A:R1C1002 4.2 14.4 1.0 C38 A:R1C1002 4.2 14.1 1.0 C19 A:R1C1002 4.2 20.1 1.0 C2 A:R1C1002 4.3 14.2 1.0 C12 A:R1C1002 4.3 19.5 1.0 C9 A:R1C1002 4.3 18.5 1.0 O2 A:DT8 4.6 19.3 1.0 C25 A:R1C1002 4.7 16.3 1.0 C13 A:R1C1002 4.7 21.8 1.0 O A:HOH2018 4.8 24.8 1.0 O A:HOH2063 4.8 42.4 1.0 C3 A:R1C1002 4.8 14.1 1.0 C18 A:R1C1002 4.8 22.4 1.0 C8 A:R1C1002 4.8 19.0 1.0 O A:HOH2037 4.9 35.5 1.0 C37 A:R1C1002 4.9 14.4 1.0 C24 A:R1C1002 5.0 14.8 1.0

V.C.Pierre, J.T.Kaiser, J.K.Barton. Insights Into Finding A Mismatch Through the Structure of A Mispaired Dna Bound By A Rhodium Intercalator. Proc.Natl.Acad.Sci.Usa V. 104 429 2007.
ISSN: ISSN 0027-8424
PubMed: 17194756
DOI: 10.1073/PNAS.0610170104